Electrochemical Degradation of the Reactive Red 141 Dye on a β-PbO2 Anode Assessed by the Response Surface Methodology

نویسندگان

  • José M. Aquino
  • Romeu C. Rocha-Filho
  • Nerilso Bocchi
  • Sonia R. Biaggio
چکیده

A degradação eletroquímica do corante Vermelho Reativo 141 foi investigada por meio da aplicação da metodologia de superfície de respostas, utilizando reator filtro-prensa com anodo de β-PbO 2 . A carga requerida para 90% de descoloração (Q) e a remoção da demanda química de oxigênio após 30 min de eletrólise (COD) foram utilizadas para modelar o sistema. As variáveis investigadas foram a densidade de corrente, pH, concentração de NaCl e temperatura. Baixos valores de Q (0,2-0,3 A h L) foram obtidos em condições ácidas (pH 1-3) e em altas concentrações de NaCl (1,0-2,0 g L), quando as espécies oxidantes Cl 2 e HOCl estão presentes. Os melhores valores para COD foram obtidos com altas densidades de corrente e em condições de pH ácido a neutro; entretanto, o consumo energético resultante torna o processo economicamente não viável. Para soluções extremamente ácidas foram obtidos valores reduzidos de consumo de energia, relacionado ao Q, em torno de 0,79 kW h m.

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تاریخ انتشار 2010